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Proton Magnetic Resonance Spectra of Some Organosulfur Compounds

Volume 19, Number 4 (July 1965) Page 105-109

Purcell, J.M.; Susi, H.

The proton magnetic resonance spectra of various sulfur derivatives of long-chain carboxylic acids have been studied The types of compounds studied include those where the methylene chain is interrupted by a sulfide or a sulfone group and those where the carboxyl group has been replaced by -SO3- or -C(= O)S-. The spectral effects produced by the sulfur-containing groups are discussed. The effect of the sulfur group in sulfides and sulfones is compared with the effect of an oxygen atom in a similar environment. The effect of the -SO3- and -C(= O)S- groups on neighboring methylene groups is compared with the effect of the carboxyl group.