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Vibrational Spectra of Triphenyl Compounds of Group VA Elements

Volume 23, Number 1 (Feb. 1969) Page 12-16

Shobatake, Kosuke; Postmus, Clarence; Ferraro, John R.; Nakamoto, Kazuo


The infrared and Raman spectra of triphenyl compounds of Group VA elements PPh3, AsPh3, SbPh3, and BiPh3 (Ph represents the phenyl group), have been reported in the 530-100 cm−1 region. The metal-phenyl stretching and bending vibrations have been assigned with the aid of approximate normal coordinate analysis and depolarization ratios of Raman lines.