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Vibrational Spectroscopy of Iodine-doped Poly(phenyl)acetylene

Volume 38, Number 2 (April 1984) Page 267-270

Ferraro, John R.; Martin, Kathleen; Furlani, Anita; Russo, Maria Vittoria


The complementation of Resonance Raman, Raman Polarization data, and far infrared spectroscopy was used to determine the nature of the iodine moiety in iodine-doped poly(phenyl)acetylene. For the molar concentration range of iodine/polymer of 1 to 5, the predominant iodine entity in the iodine-doped conductive polymer appears to be I5.