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Vibrational Spectra and Normal Coordinate Treatment of Bis(2-ethylhexyl)phosphoric Acid

Volume 23, Number 5 (Oct. 1969) Page 521-527

Nakamoto, K.; Ferraro, J.R.; Mason, G.W.


The infrared and Raman spectra of the bis(2-ethylhexyl)phosphoric acids [(C8H17O)2PO(OH), (C8H17O)2PO(OD)] and its sodium salt (C8H17O)2PO(ONa) were obtained from 4000-100 cm−1. On the basis of an approximate normal coordinate treatment and using a cyclic dimeric model, theoretical band assignments were made. These results were compared with those obtained for dimethylphosphinic acid.