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Metal Isotope Effect on Raman Spectrum of [Zn(NH3)4]I2 Crystals

Volume 25, Number 3 (June 1971) Page 352-355

Nakamoto, Kazuo; Takemoto, James; Chow, T.L.


The Raman spectra of [64Zn(NH3)4]I2 and its 68Zn analog have been measured in the crystalline state. The Zn-N stretching vibrations have been assigned based on the observed metal isotope shifts. These shifts have been compared with theoretical values obtained from a complete normal coordinate analysis on the [Zn(NH3)4]2+ ion.