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Identification of the OO Stretching Frequency in Some Fluoroperoxides by Raman Spectroscopy

Volume 26, Number 3 (June 1972) Page 381-384

Melveger, A.J.; Anderson, L.R.; Ratcliffe, C.T.; Fox, W.B.


The O—O stretching frequency in a series of fluoroperoxides was identified by Raman spectroscopy. This vibration is usually the most intense in the Raman spectrum and is highly polarized. The value of the peroxide stretching frequency was found to depend on the electro-negativity of attached groups.