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The Charge Transfer to Solvent (CTTS) Spectrum of Br In Molten Tetrabutylphosphonium Tetrabromometalates

Volume 27, Number 5 (Oct. 1973) Page 394-394

Sundheim, B.R.; Islam, N.


Recently we reported that some of the charge-transfer bands of CoBr4= which are ordinarily obscured by the absorption of Br can be resolved in thin films of (Bu4P+)2CoBr4=.1 Apparently the concentration of free Br is so small under these conditions that it permits the detection of CoBr4= bands in the same region. Here we note that it is also possible to observe at least the first component of the absorption band of Br by the same technique.