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Infrared and Raman Spectra of Bis--Diketonates of Palladium (II)

Volume 32, Number 2 (April 1978) Page 151-157

Bulkin, Bernard J.; Rose, Rose K.

Infrared and Raman data are reported for four palladium-β-diketonates, including the bis-acetylacetonate, bis-1-phenyl-1,3-butanedionato trans chelate, as well as the cis and trans isomers of 1-p-octyloxyphenyl-1,3-butanedionato chelates. The data indicate that a straightforward application of local symmetry selection rules for the —PdO4— subunit is adequate to explain the low frequency infrared and Raman spectra.