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Gas Chromatography/Matrix Isolation-Infrared Spectrometry for the Identification of Polycyclic Aromatic Hydrocarbons in Urban Air Particulate Matter
Volume 43, Number 8 (Dec. 1989) Page 1344-1349
Childers, Jeffrey W.; Wilson, Nancy K.; Barbour, Ruth K.
The capabilities of gas chromatography/matrix isolation-infrared (GC/MI-IR) spectrometry for detecting and identifying polycyclic aromatic hydrocarbons (PAHs) in urban air particulate matter are demonstrated. The ability of GC/MI-IR to discriminate between PAH isomers that are difficult to distinguish by conventional electron-impact ionization gas chromatography/mass spectrometry is shown. The MI-IR spectra of PAHs obtained under GC/MI-IR conditions are comparable to those reported in the literature that were obtained by using slow-spray-on matrix deposition techniques.