The following is an abstract for the selected article. A PDF download of the full text of this article is available here. Members may download full texts at no charge. Non-members may be charged a small fee for certain articles.

Benzene in Zeolite ZSM-5 Studied by Diffuse Reflectance Infrared Spectroscopy

Volume 44, Number 6 (July 1990) Page 1070-1073

Wang, H. Paul; Yu, T.; Garland, Ben A.; Eyring, Edward M.

The behavior of benzene molecules in ZSM-5 has been studied in detail with the use of diffuse reflectance FT-IR spectroscopy. The infrared difference spectra indicate that benzene molecules have a high selectivity for adsorption first on the most energetic (Brönsted acid) ZSM-5 sites. The existence of at least two adsorbed benzene species has also been confirmed by infrared spectroscopy. Deuterated benzene (C6D6) species located at the ZSM-5 channels and channel intersections are characterized by the C-D stretching vibrations at 2284 and 2276 cm−1, respectively. Since the high symmetry (D6h) of the adsorbed benzene molecules is preserved, the framework of ZSM-5 may have been distorted. The distortion of the framework of ZSM-5 is also indicated by the red shift of the Si-O (or Al-O) asymmetric stretching vibrations (at ~1215 cm−1) when adsorbed benzene molecules are present.