holder

The following is an abstract for the selected article. A PDF download of the full text of this article is available here. Members may download full texts at no charge. Non-members may be charged a small fee for certain articles.


Determination of Parts-per-Trillion Levels of Chlorate, Bromate, and Iodate by Electrospray Ionization/High-Field Asymmetric Waveform Ion Mobility Spectrometry/Mass Spectrometry

Volume 53, Number 11 (Nov. 1999) Page 1367-1374

Barnett, David A.; Guevremont, Roger; Purves, Randy W.


An electrospray ionization (ESI) source was used to transfer oxo-anions (XO3-) of nitrogen, chlorine, bromine, and iodine to the gas phase for analysis by a combination of high-field asymmetric waveform ion mobility spectrometry (FAIMS) and mass spectrometry. The combination of ESI with FAIMS and mass spectrometry (ESI-FAIMS-MS) yields mass spectra that are virtually free of common spectral interferences. The unique separation and focusing properties of the FAIMS analyzer improved signal-to-background ratios (S/B) for all these analytes by 3-4 orders of magnitude compared with conventional ESI-MS and produced parts-per-trillion (pptr) detection limits for ClO3-, BrO3-, and IO3- in methanolic solution.