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Investigation of Time-Dependent Phenomena by Use of Step-Scan FT-IR

Volume 47, Number 9 (Sept. 1993) Page 1297-1310

Palmer, Richard A.; Chao, James L.; Dittmar, Rebecca M.; Gregoriou, Vasilis G.; Plunkett, Susan E.

The development, during the last decade, of modern step-scan interferometry instrumentation has allowed FT-IR to be applied to the study of time-dependent phenomena in ways not previously possible, because of the problems of uncoupling the spectral multiplexing from the temporal domain in the continuous-scan FT-IR mode. Specifically, the time regime from tens of nanoseconds to tens of milliseconds has been accessible to time-domain measurements to only a very limited degree with continuous-scan instrumentation and not at all for modulation-demodulation (frequency-domain) experiments in this time range. The step-scan technique not only works very well in this time regime and for slower phenomena, but is only prevented from application to faster processes by the signal strength, the speed of available detectors, the intensity of sources, and the speed and sophistication of the electronics. This paper surveys the various types of experiments which are either enhanced by use of step-scan FT-IR methods or are only possible by use of these techniques. The principles of step-scan instrumentation are reviewed, particularly those of retardation control, signal generation, and data acquisition, as well as the place of step-scan FT-IR relative to other techniques of dynamic vibrational spectroscopy. The importance of path difference (phase) modulation, particularly in frequency-domain measurements, the extraction and use of the signal phase, the creation of 2D FT-IR spectra, and the strategies for acquisition of both time- and frequency-domain data in the step-scan mode are discussed and illustrated.