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Overtone Spectra of CHD3 with an FT-IR Spectrometer Aided by Infrared Double Resonance

Volume 47, Number 12 (Dec. 1993) Page 2058-2060

Mizugai, Yoshihiro; Klaassen, Jody J.; Roche, Christine; Steinfeld, Jeffrey I.


We have used a time-resolved double-resonance (pump-probe) method to assign the CHD3 spectra taken by an FT-IR spectrometer at high resolution. The spectra of 2v3, v3 + v6, and 2v6 around 2000 cm−1 were investigated. Collisional processes in the molecule were investigated by the time evolution of the signal and double-resonance spectra.