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Electron Paramagnetic Resonance Studies of Impurity Defects in PbTiO3

Volume 51, Number 1 (Jan. 1997) Page 117-122

Keeble, D.J.; Poindexter, E.H.; Gerardi, G.J.


Electron paramagnetic resonance studies of metal ion impurities in the perovskite titanate PbTiO3 are presented. Results for Pt+3, Mn+4, and Cu+2 are given, and near-neighbor superhyperfine structure (shfs) splittings for the first Pb shell are reported for these ions at low temperature. The relation between the shfs and the local structure of the ion is discussed.